自组装铝/氧化铜和铝/氧化铁及其性能评估

本文分别采用模板法制备氧化铜纳米花, 水热法制备氧化铁纳米环, 并自组装制备了铝-氧化铜和铝-氧化铁2种铝热剂。自组装增大了异相材料之间的接触, 分别使得铝-氧化铜的反应放热量和压力由523 J·g^-1、1 858 kPa增加至1 069 J·g^-1、 4 389 kPa;铝-氧化铁的反应放热量和压力由1 448 J·g^-1、749 kPa增加至2 039 J·g^-1、2 280 kPa。两种铝热剂的放热量和压力差别较大, 且铝-氧化铜的静电感度高于大多数含能材料, 铝-氧化铁的撞击感度特别低, 显示出不同的应用特点。     

Flow and Dynamic Viscoelastic Characterization of Non-Purified and Purified Mucin Dispersions

This study demonstrated that the rheological behavior of mucin, a glycoprotein, mainly depends on the concentration of its dispersions and purity of the sample. Rheological properties were studied under rotational and oscillatory shear and creep curves. The results showed that mucin dispersions display non-Newtonian behavior of the shear thinning type. The mucin dispersion showed an apparent viscosity ranging from 0.22 to 29.29 Pa.s; at 10% concentration it formed macromolecular solutions with G″>G′; these showed viscoelastic liquid behavior, while at 40% it showed viscoelastic solid behavior, characteristic of weak gels, G′>G″. Atomic force microscopy revealed topographical differences on the commercial mucin surface, as in non-purified and purified mucin gels.     

微量元素与煤有机质的结合关系浅探——以太原西山矿区8号煤层为例

对太原西山矿区8号煤层的肥、焦、瘦、贫等不同烟煤的镜煤组分进行了酸洗脱灰处理,并同时对这些酸洗后的样品进行了红外分峰处理和微量元素含量的测定,发现随着煤的变质程度加深,某些有机基团与某些微量元素呈正相关关系,并因其正相关系数很高而结合的可能性很大;有的呈负相关关系;也有的和微量元素部分呈正相关变化部分则呈负相关变化。因此,将煤的有机基团分为三类:微量元素亲和性有机基团、微量元素憎厌性有机基团和对微量元素既无亲和性也无憎厌性的中性有机基团。微量元素和煤的有机基团之间相互选择性很强。但无论表现为典型的亲和性还是憎厌性,其亲和、憎厌程度的变化波动趋势,均遵循一个统一的变化规律——元素周期律。典型的中性有机基团,对亲石元素和亲铁亲铜元素所表现的亲和、憎厌倾向也有明显不同,有一定的规律可循。煤中不同类型的有机基团和微量元素的正负相关性,即对微量元素的亲和和憎厌性,对元素周期律的响应型式和响应程度差别也很大。     

The geometry of the secant caustic of a planar curve

The secant caustic of a planar curve M is the image of the singular set of the secant map of M. We analyze the geometrical properties of the secant caustic of a planar curve, i.e. the number of branches of the secant caustic, the parity of the number of cusps and the number of inflexion points in each branch of this set. In particular, we investigate in detail some of the geometrical properties of the secant caustic of a rosette, i.e. a smooth regular oriented closed curve with non-vanishing curvature.     

Dynamics of an intraguild predation food web model with strong Allee effect in the basal prey

Since intraguild predation (IGP) is a ubiquitous and important community module in nature and Allee effect has strong impact on population dynamics, in this paper we propose a three-species IGP food web model consisted of the IG predator, IG prey and basal prey, in which the basal prey follows a logistic growth with strong Allee effect. We investigate the local and global dynamics of the model with emphasis on the impact of strong Allee effect. First, positivity and boundedness of solutions are studied. Then existence and stability of the boundary and interior equilibria are presented and the Hopf bifurcation curve at an interior equilibrium is given. The existence of a Hopf bifurcation curve indicates that if competition between the IG prey and IG predator for the basal resource lies below the curve then the interior equilibrium remains stable, while if it lies above the curve then the interior equilibrium loses its stability. In order to explore the impact of Allee effect, the parameter space is classified into sixteen different regions and, in each region, the number of interior equilibria is determined and the corresponding bifurcation diagrams on the Allee threshold are given. The extinction parameter regions of at least one species and the necessary coexistence parameter regions of all three species are provided. In addition, we explore possible dynamical patterns, i.e., the existence of multiple attractors. By theoretical analysis and numerical simulations, we show that the model can have one (i.e. extinction of all species), two (i.e. bi-stability) or three (i.e. tri-stability) attractors. It is also found by simulations that when there exists a unique stable interior equilibrium, the model may generate multiple attracting periodic orbits and the coexistence of all three species is enhanced as the competition between the IG prey and IG predator for the basal resource is close to the Hopf bifurcation curve from below. Our results indicate that the intraguild predation food web model exhibits rich and complex dynamic behaviors and strong Allee effect in the basal prey increases the extinction risk of not only the basal prey but also the IG prey or/and IG predator.     

三次Pythagorean Hodograph 曲线在给定总弧长下的$G^2$拼接

Pythagorean-hodograph (PH)曲线因其在弧长和等距线计算方面的优势而被广泛应用于曲线建模中.本文讨论了在总弧长约束下的三次PH曲线$G^2$连续拼接问题.具体地说,给定两个端点和一个拼接点,构造两条三次PH曲线,使其在指定总弧长下插值两个端点,并且在连接点处是$G^2$连续的.这也可以看作是一个曲线延拓问题.根据三次PH曲线的弧长公式和$G^2$连续条件,最终将问题转化为了一个带有约束的极小值问题,同时我们给出了几个具体例子来说明该方法.     

太阳能分光发电系统的光学薄膜滤波片设计与仿真

由于不同材料的禁带宽度不同,对太阳光谱的吸收曲线也各不相同,探讨了用等效折射概念设计滤光片的原理和计算方法.针对非晶硅、单晶硅和砷化镓的吸收谱线设计了一组短波通滤光片,滤波片A在波长380～800nm处,平均透射率T＞90％;在波长880～1100 nm处截止,平均透射率T＜1％;滤波片B在380～500 nm处T＞9...     

薄膜光学常数的椭偏测量

利用光谱型椭偏仪测量了镀在熔石英玻璃基片上的氟化镁薄膜在300～850nm波长范围内的椭偏参数.并利用Levenberg-Marquardt算法.反演出了氟化镁薄膜在该波长范围内的色散曲线.通过与纯氟化镁体材料的色散曲线比较,发现所镀的氟化镁薄膜的折射率略小于体材料的折射率.     

碱性品红在可见光波段反常色散的研究

通过观察可见光波段品红溶液的色散,绘制色散曲线,分析品红溶液在可见光波段出现的反常色散现象,验证关于反常色散的理论.并主要针对出现反常色散的波段进行研究,得出出现反常色散的波段范围.